stainless Steel and Duplex Pipe (ASTM A312, A790)

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这ASTM A312 specification covers seamless and welded austenitic stainless steel pipes used for high temperature and/or corrosive service (the most common grades are 304/304L and 316/316L). The A790 specification covers seamless duplex and super duplex pipes UNS S32205/31803 and UNS S32750/32760 (special SS grade with a mixed ferritic/austenitic microstructure). In this article, we illustrate the chemical and mechanical properties of the A312/A790 specifications

sTAINLESS STEEL PIPE ASTM A312

stainless steel pipes are used for high-temperature applications where corrosion is a key issue.
在本世纪初开发了不锈钢,以应对许多行业的需求不断增长,以应对可以承受要求苛刻的服务条件的更耐用的钢。不锈钢被认为是标准碳钢的演变,并通过将合金元素添加到镍和铬等基础铁中获得。这种合金元素的添加增强了钢对严酷应用中腐蚀的阻力。
在挖掘不同等级之前,让我们回顾市场上可用的不锈钢类型及其分类。
stainless steel pipes ASTM A312 TP304 TP316

sTAINLESS STEEL TYPES

通常,任何至少有10.5%铬的钢合金都可以被视为不锈钢。然而,根据合金元素(镍,莫利,钛,钛,铜,氮等)的混合,可以提供多种等级。每种合金具有特定的结构以及化学和机械性能。

不锈钢的一般属性是,由于氧化铬的外部铬层,它们表现出对腐蚀的抗性。这种氧化物的作用像是微观保护层,与氧气反应并阻断腐蚀。此外,不锈钢合金在低温应用中具有更好的韧性,比碳钢,更好的强度和硬度,改善的延展性和低维护成本。

stainless steels may be grouped into a few families, designated as “series”. Let’s take a closer look.

Austenitic Stainless Steel (Series 300)

这se are the most common grades of stainless steel. The microstructure of austenitic stainless steels is obtained with the addition of nickel, manganese, and nitrogen that give weldability and formability properties to the alloy. The resistance to corrosion can be further improved by augmenting the percentage of chrome, moly, and nitrogen to the base alloy.

然而,基本的奥氏体等级容易受到应力腐蚀破裂的影响(镍的比例较高以增强应激腐蚀破裂)。奥氏体不锈钢不能通过热处理加固,但可以使高强度水平锻炼,同时保持合理的强度和延展性水平。

Even if austenitic steels are generally non-magnetic, they can show some magnetic property based on the actual alloy composition and the work hardening given during production. Austenitic stainless steels are divided into the series 200 (chromium-manganese-nickel alloys) and 300 (chromium-nickel alloys like 304, 309, 316, 321, 347, etc). Grade 304/304L is the most common austenitic stainless steel that suits most corrosive applications. Any other grade in the 300 series enhances the basic features of SS304.

马氏体不锈钢(系列400)

Martensitic stainless steels are similar to ferritic steels as they both have remarkable chromium content, however, martensitic steels have higher carbon content up to 1%. The high carbon content allows martensitic steels to be hardened and tempered as standard carbon and chrome alloy steels (but show generally low weldability and ductility).

This type of stainless steel is specified in case of high strength and moderate corrosion resistance requirements. Different from standard austenitic stainless steels, martensitic grades are magnetic. Common martensitic grades are 410, 420 and 440C.

Ferritic Stainless Steel (SS430)

铁素体不锈钢具有明显的铬含量,但碳的添加较低(通常低于0.1%)。这个不锈钢家族的名称来自这样一个事实,即它们的微观结构与碳和低合金钢非常相似。

这se steels have a wide range of application, except for thin surfaces as they have low resistance to welding or applications requiring formability (ferritic steels show low formability and ductility). Ferritic stainless steels cannot be hardened by heat treatment. By adding moly to a ferritic grade, the steel can be used in highly aggressive applications as desalination plants and seawater.

这些钢表现出对应力腐蚀破裂的显着抗性。同样,马氏体钢,铁素体SS是磁性的。最常见的铁素体等级是430(17%铬)和409(11%铬),在汽车部门主要使用。

Duplex and Super Duplex Stainless Steel (UNS S32205, S31803, S32750/760)

Duplex stainless steels have a microstructure which is 50% ferritic and 50% austenitic. This composition gives them a better strength than either ferritic or austenitic steels. Further details about this topic are given below (see ASTM A790 pipes).

precipitation hardening (PH 17-4)

pH钢可以具有明显的强度,因为在合金中加入铜,niobium和铝。

在最终老化治疗之前,可以将这些钢加工成具有高公差要求的非常特异的形状。这与在治疗过程中会造成失真的Martensitic钢的常规硬化和回火不同。

这resistance to corrosion of. precipitation hardening steels are comparable to standard austenitic steels like SS304.
这most common precipitation hardening stainless steel is the 17-4PH, which features 17% chromium and 4% nickel.

不锈钢管等级图(ASTM A312)

这table shows the chemical composition of the most common grades of stainless steel pipes under the ASTM A312-ASME SA312 specification:

SS管道等级 联合国 C Mn p s si cr Ti NB n
TP304 S3040 0.08 2.0 0.045 0.030 1.0 18.0-20.0 8。0-11.0
TP304L S30403 0.035 2.0 0.045 0.030 1.0 18.0-20.0 8。0-13.0
TP304H S30409 0。04-0.10 2.0 0.045 0.030 1.0 18.0-20.0 8。0-11.0
TP304N S30451 0.08 2.0 0.045 0.030 1.0 18.0-20.0 8。0-18.0 0.10-0.16
TP304Ln S30453 0.035 2.0 0.045 0.030 1.0 18.0-20.0 8.0 - -12.0 0.10-0.16
TP309S S30908 0.08 2.0 0.045 0.030 1.0 22.0-24.0 12。0-15.0 0.75
TP309H S30909 0。04-0.10 2.0 0.045 0.030 1.0 22.0-24.0 12。0-15.0
TP309Cb S30940 0.08 2.0 0.045 0.030 1.0 22.0-24.0 12。0-16.0 0.75 10xC min
1.10最大
TP309HCb S30941 0。04-0.10 2.0 0.045 0.030 1.0 22.0-24.0 12。0-16.0 0.75 10xC min
1.10最大
TP310S s3108 0.08 2.0 0.045 0.030 1.0 24。0-26.0 19.0-22.0 0.75
TP310H s3109 0。04-0.10 2.0 0.045 0.030 1.0 24。0-26.0 19.0-22.0
TP310Cb s31040 0.08 2.0 0.045 0.030 1.0 24。0-26.0 19.0-22.0 0.75 10xC min
1.10最大
TP310HCb s31041 0。04-0.10 2.0 0.045 0.030 1.0 24。0-26.0 19.0-22.0 0.75 10xC min
1.10最大
tp316 S3160 0.08 2.0 0.045 0.030 1.0 16.0 - -18.0 11.0-14.0 2.0-3.0
tp316l S31603 0.035 2.0 0.045 0.030 1.0 16.0 - -18.0 10.0-14.0 2.0-3.0
TP316H S31609 0。04-0.10 2.0 0.045 0.030 1.0 16.0 - -18.0 11.0-14.0 2.0-3.0
tp316Ti S31635 0.08 2.0 0.045 0.030 0.75 16.0 - -18.0 10.0-14.0 2.0-3.0 5x
(C-N)
-0.70
0.10
tp316n S31651 0.08 2.0 0.045 0.030 1.0 16.0 - -18.0 10.0-14.0 2.0-3.0 0.10-0.16
tp316ln S31653 0.035 2.0 0.045 0.030 1.0 16.0 - -18.0 11.0-14.0 2.0-3.0 0.10-0.16
tp317 S3170 0.08 2.0 0.045 0.030 1.0 18.0-20.0 10.0-14.0 3。0-4.0
tp317l S31703 0.035 2.0 0.045 0.030 1.0 18.0-20.0 11.0-15.0 3。0-4.0
tp321 s3210 0.08 2.0 0.045 0.030 1.0 17.0-19.0 9.0-12.0 0.10
tp321H s32109 0。04-0.10 2.0 0.045 0.030 1.0 17.0-19.0 9.0-12.0 0.10
tp347 s3470 0.08 2.0 0.045 0.030 1.0 17.0-19.0 9.0-13.0
tp347H s34709 0。04-0.10 2.0 0.045 0.030 1.0 17.0-19.0 9.0-13.0
tp347LN s34751 0.05-0.02 2.0 0.045 0.030 1.0 17.0-19.0 9.0-13.0 0.20-
50.0
0.06-0.10
tp348 s3480 0.08 2.0 0.045 0.030 1.0 17.0-19.0 9.0-13.0
tp348H S34809 0。04-0.10 2.0 0.045 0.030 1.0 17.0-19.0 9.0-13.0

A312 SS PIPES MECHANICAL PROPERTIES

SS管道等级
ASTM A312/ASME SA312
抗拉强度
N/MM2(最小)
产量强度
N/MM2(最小)
伸长
%(min)
TP304 515 205 35
TP304L 485 170 35
tp316 515 205 35
tp316l 485 170 35
tp321 OD <17,1 mm - 515; OD < 17,1 mm – 205; 35
OD> 17,1毫米 - 485 OD > 17,1 mm – 170

交叉参考表ASTM/EN不锈钢材料用于管道

stainless Steel Pipe Grades
werkstoff/din EN grades ASTM等级
1。4541 x6crniti18-10 A 312 Grade TP321
1。4571 X6CRNIMOTI17-12-2 312级TP316TI
1。4301 X5CrNi18-10 A 312 Grade TP304
1。4306 X2CRNI19-11 312级TP304L
1。4307 X2CRNI18-9 312级TP304L
1。4401 X5CRNIMO17-12-2 A 312 Grade TP316
1。4404 X2CrNiMo17-13-2 312级TP316L
1。4462 X2CrNiMoN22-5-3 联合国s31803(Duplex)
1。4529 X1NiCrMoCuN25-20-7 UNS N 08926
1。4539 x1nicrmocu25-20-5 UNS N 08904(904L)
1。4547 X1CRNIMOCUN20-18-7 联合国s31254

ASTM A312 PIPE DIMENSIONS

这standard stainless steel pipes dimensions are set by theANSI ASME B36.19 specification

无缝的SS管有尺寸范围1/8英寸到达24英寸,焊接不锈钢管在2英寸至36英寸的范围内生产(ASTM A312,ASTM A358,即电融合焊接的无液压镀和无的无用的无污水镀铬的钢铁钢管,或滚动)。

ASTM A312管道重量

名义管尺寸 Outside Diameter 不锈钢管尺寸
附表5s schedule 10S schedule 40S 附表80s
(毫米) (inch) wt /重量
mm(in) kg/m mm(in) kg/m mm(in) kg/m mm(in) kg/m
1/8 10.3 0.405 - - 1.25(0.049) 0.28 1.73(0.068) 0.37 2.42(0.095) 0.47
1/4 13。7 0.540 - - 1.66(0.065) 0.49 2.24(0.088) 0.63 3.03(0.119) 0.80
3/8 17.2 0.675 - - 1.66(0.065) 0.63 2。32(0.091) 0.85 3.20(0.126) 1.10
1/2 21.3 0.840 1.65(0.065) 0.81 2.11(0.083) 1.00 2.77(0.109) 1.27 3.74(0.147) 1.62
3/4 26。7 1.050 1.65(0.065) 1.02 2.11(0.083) 1.28 2.87(0.113) 1.68 3.92(0.154) 2.20
1 33.4 1.315 1.65(0.065) 1.30 2.77(0.109) 2.09 3.38(0.133) 2.50 4。55(0.179) 3.24
11/4 42.2 1.660 1.65(0.065) 1.66 2.77(0.109) 2.69 3.56(0.140) 3。39 4.86(0.191) 4。47
11/2 48。3 1。900 1.65(0.065) 1.91 2.77(0.109) 3.11 3.69(0.145) 4.06 5.08(0.200) 5。41
2 60.3 2.375 1.65(0.065) 2.40 2.77(0.109) 3。93 3.92(0.154) 5。45 5。54(0.218) 7.49
21/2 73.0 2。875 2.11(0.083) 3。69 3.05(0.120) 5。26 5.16(0.203) 8.64 7.01(0.276) 11。4
3 88.9 3。500 2.11(0.083) 4。52 3.05(0.120) 6。46 5.49(0.216) 11。3 7.62 (0.300) 15。3
31/2 101.6 4.000 2.11(0.083) 5。18 3.05(0.120) 7.41 5.74(0.226) 13。6 8.08(0.318) 18。6
4 114.3 4。500 2.11(0.083) 5。84 3.05(0.120) 8。37 6。02(0.237) 16。1 8.56(0.337) 22.3
5 141。3 5。563 2.77(0.109) 9.46 3.41(0.134) 11.6 6.56(0.258) 21.8 9.53 (0.375) 31.0
6 168.3 6.625 2.77(0.109) 11。3 3.41(0.134) 13。9 7.12 (0.280) 28。3 10.9(0.432) 42.6
8 219.1 8.625 2.77(0.109) 14。8 3.76(0.148) 20.0 8.18(0.322) 42.5 12。7 (0.500) 64.6
10 273.1 10.750 3.41(0.134) 22.7 4。20(0.165) 27.8 9.28 (0.365) 60.4 12。7 (0.500) 81。5
12 323.9 12.750 3。97 (0.156) 31.3 4.58(0.180) 36。1 9.53 (0.375) 73.9 12。7 (0.500) 97.4

A312管道直径耐受性

nps ASTM A312/ASME SA312 OD Tolerance
+ -
英寸 毫米 英寸 毫米
1/8 1 1 / 2
> 1 1/2至4
> 4 to 8
> 8 to 18
> 18 to 26
> 26至34
> 34至48
1/64(0.015)
1/32(0.031)
1/16(0.062)
3/32(0.093)
1/8(0.125)
5/32(0.156)
3/16(0.187)
0.4
0.8
1.6
2.4
3.2
4.0
4.8
1/32(0.031)
1/32(0.031)
1/32(0.031)
1/32(0.031)
1/32(0.031)
1/32(0.031)
1/32(0.031)
0.8
0.8
0.8
0.8
0.8
0.8
0.8

A312 PIPE WALL THICKNESS TOLERANCE

这nominal wall thickness tolerance is +/- 12.5%.

nps ASTM A312/ASME SA312 WT Tolerance, %
+ -
1 /8-2 1/2 20.0 12。5
3〜18,t/d≤5% 22.5 12。5
3〜18,t/d> 5% 15。0 12。5
≥ 20, welded 17.5 12。5
≥20,无缝,t/d≤5% 22.5 12。5
≥20,无缝,T/D> 5% 15。0 12。5

A312 SS PIPE FINISHING AND TESTING

抛光 制造商可以将任何不锈钢管涂成#4抛光剂,#6抛光剂,#7抛光剂或#8镜面饰面。
铜ttings stainless steel pipes can be produced in standard lengths or cut to size (standard lengths are 20′ and 40′ depending on the nominal pipe size).
Beveling Manufacturers can bevel the edges of stainless steel pipes to prepare them for welding.
Threading 不锈钢管还可以提供,除了平整和斜面的末端,还带有螺纹末端(通常适用于2英寸以下的NP)
珩磨管& Turning 制造商可以使用精确的磨损工具磨练SS管道和管,并获得任何所需的表面处理或尺寸耐受性。
Heat treating & Annealing 大多数不锈钢管等级都可以进行热处理以修饰其机械性能。
positive Material Identification (PMI) Manufacturers can perform PMI testing to ascertain the actual content of Nickel, Chrome, and Moly in the pipe.
UT测试 In some cases, UT testing of the stainless steel plates may be required.

我们建议从ASTM websiteor theIHS store要完全了解这个话题。

双工管道

A duplex pipe features, at the same time, the qualities of a ferritic SS pipe (high resistance to corrosion cracking and tensile strength) and of an austenitic SS pipe (easy manufacturing and good resistance to corrosion and erosion). Duplex pipes 2205 (UNS S31803/UNS S32205) are used for applications below 600 degrees (F).

Duplex and super duplex pipes ASTM A790

双链体和超级双链不锈钢是可焊接的,具有中等的形成性。这些类型的不锈钢是磁性的,但由于50%的奥氏体含量而导致的铁素体,马氏体和降水硬化等级的程度较低。

这common grades under this family are:

  • 精益复式:联合国s32101, S32202 (UR2202), S32304, and S32003.
  • 标准双工:UNS S31803/S32205
  • 超级双工:UNS S32760(Zeron 100),S32750(2507)和S32550(Ferralium 255)
  • 超双层:联合国s32707 and S33207

ASTM A790specification covers seamless duplex and super duplex pipes for demanding applications, with high corrosion, temperature, and pressure. Electro-fusion welded duplex and super duplex welded pipes are covered, instead, by theASTM A928 specification

双链体和超级双链体可以被视为“高级”不锈钢管,并且可以在市场上可在相同尺寸的常规A312不锈钢管道(由ASME B36.19规格覆盖的尺寸范围)中获得。

这re are a few differences between duplex/super duplex pipes and conventional stainless steel pipes, which are explained below.

什么是双工钢?

“双链”一词是指具有双重结构的不锈钢家族 - 即它们既不是完全奥氏体的SS结构,例如304不锈钢,也不是标准铁素体(例如430系列)。

Duplex stainless steel (UNS S31803/UNS S32205) has been developedto overcome the issues of the 300 series stainless steelsAS 316L和317L(在金属暴露于含有氯化物的液体或通过钢暴露于高温下的液体的情况下,在拉伸应力下的氯化应力腐蚀开裂)。

双链钢的微观结构由连续铁氧体相(约40-50%铁氧体)包围的奥氏体池组成。

因此,双链管结合铁素体和奥氏体不锈钢材料的品质。

联合国2205duplex steel finds application in marine projects, oil & gas exploration, closed loops water systems, desalinization plants, hydrocarbons storage and transportation, downstream refining, pulp, and paper.

Duplex are resistant to stress corrosion cracking. While standard duplex steels have corrosion resistance comparable to standard austenitic steels (but show better strength and resistance to stress-corrosion-cracking), the so-called super duplex steels feature enhanced strength and resistance to any type of corrosion compared to standard austenitic steels.

DUPLEX CORROSION RESISTANCE

双相不锈钢显示了优越的腐蚀resistance to grade 316 for most applications (excellent resistance to localized corrosion including intergranular, pitting and crevice corrosion; the CPT of 2205 is generally at least 35ºC). Duplex is also resistant to chloride corrosion cracking (SCC) at temperatures up to about 150ºC.

2205级双链体通常会在导致标准的300级不锈钢的标准奥氏体等级过早失败的环境中表现良好。与不锈钢316相比,它对海水腐蚀具有更强的抵抗力。

请注意,尽管双链不锈钢表现出良好的高温氧化耐药性,但如果在一段时间内保持在300ºC以上的温度下,则有2205次遭受封闭状态。(这种情况只能通过完整的溶液退火处理来纠正)。

For this reason, Duplex stainless steels are never used for temperatures in excess of 300ºC. Duplex pipes match the following fittings materials: ASTM A815 (butt weld fittings) and ASTM A182 F51 / F53 / F55 (flanges / forged socket weld – threaded fittings).

A790双链管特性

联合国 化学成分 Min.tensile(KSI) Min.Yield
(KSI)
伸长
联合国s31803 C0。30max
CR 21.0-23.0
Mn2.00max
莫2.50-3.50
n0.08-0.20
NI 4.50-6.50
p 0.030最大
s 0.020最大
si 1.00 max
90 65 25
UNS S32205 C0。30max
cr22.0-23.0
Mn2.00max
莫3。00-3.50
n 0.14-0.20
NI 4.50-6.50
p 0.030最大
s 0.020最大
si1.00 max
95 65 25

Duplex pipes are manufactured according to the ASME B36.19 standard.

超级复式管

wHAT IS SUPER DUPLEX?

super duplex stainless steel is a variation of the duplex steel alloy which is used in the oil & gas, chemical, power generation, mechanical and desalination industries:

  • oil & gas production equipment
  • Offshore platforms
  • heat exchangers
  • process and service water systems
  • 消防系统
  • 注入和压载水系统
  • piping
  • 高压RO植物和海水管道
  • 机械应用中的高强度和耐腐蚀零件
  • FGD系统(发电)
  • Utility and industrial scrubber systems
  • 吸收塔

这higher chromium and molybdenum content of Super Duplex vs. Duplex makes it extremely resistant to uniform corrosion by organic acids like formic and acetic acid.
super Duplex also provides excellent resistance to inorganic acids, especially those containing chlorides.
由PREN = Cr + 3.3mo + 16N计算的超级双链体的凹痕电阻等效物在大多数材料形式中将超过40。

A790超级双面管道属性

联合国 化学成分 最小的
(KSI)
Min.Yield
(KSI)
伸长
联合国s32750 C最大0.030
cr
24。0-26.0
0。5max
Mn1。20max
3。0-5.0
n0。24-0.32
6.0-8.0
p0.035max
s0.020马克思
si0.8max
116 80 15
UNS S32760(“ Sandvik”) C最大0.03
cr
24。0-26.0
0.5-1.0
Mn1.0最大
3。0-4.0
n0。2-0.3
6.0-8.0
p最大0.03
s0。01max
si1.0最大
w0.5-1.0
109 80 25

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9 Responses

  1. Hi,
    非常有用和最新信息。我想用一个“传奇”一词说,来源的积累并以一种很好的方式描述它。感谢您分享并将知识传播到金属行业!
    All the very best.

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